Now when I read it again, you are right you did! Infact both HW and CH zone valves are configured in the Hot Water configuration set-up in evohome. That's the bit that threw me a bit.
I also made some progress as to why both me and my trained installer couldn't work out how to install the HW Kit on my Vaillant Unistor. As it happens, I have one of the earlier versions of the Vaillant Unistor that doesn't have a free dry pocket for the NTC sensor, as shown in Vaillant's own instruction manuals. Instead I need to remove the cylinder controls completely and that frees up a dry pocket that I should be able to use for the Honeywell HW kit. Guess where I found that out, in the Vaillant VR65 manual. I went there only because I wondered how Vaillant themselves used an NTC probe as part of their boiler and cylinder eBUS configuration.
Now the only open question is whether my UK Vaillant boiler will recognise the Dutch Vaillant Opentherm module VR33. That's on it's way to me now. So only time will tell.
Can either Stuart or top brake tell me how they confirmed if Opentherm was working between the boiler and the OT Bridge?