Do you guys not think the original poster might have been scared away. :O
Anyway, Plavixo, to get you started, have a look at the HomeEasy range. It communicates wirelessly, and is sold in HomeBase (and other places) for very reasonable prices. Specifically you need to use the HE105 Heating Control module. Plus a remote control from its range of course.
To control it remotely and/or to program it, try this product here - http://www.automatedhome.co.uk/New-P...Your-Home.html It is a USB stick that you can plug into your Windows Server in the loft. It comes with software that allows you to schedule events (on/off). You can also write a simple web page (IT graduates, right?) to interact with its software to control devices.
After that you might want to expand to its other products. Hope it helps!!
Note - it is only a simple system, but if you are just starting out, it is brilliant!