Ahh - I wondered whether a bound TRV and a bound boiler relay could talk to each other directly.
I suppose it would be easy to find out - pull the batteries from the controller and see if things continue to operate!
Even if the TRVs are calling for heat via the controller it could just be as a mesh type network (relaying commands without actually looking at them).
Who know.... Come on @Rameses, give us the details!
P.