Guilty! I've just looked at the evohome installation guide (2014 edition) and in the "Step 3: Power up & bind devices" the sequence is:
HR92Rad controllers...
CS92Wireless Cylinder Stat...
BDR91 to control boiler...
R8810OpenTherm Bridge...
BDR91to control Zone Valve...
HR80Radiator Controller...
HCE80 or HCC80...Underfloor heating controller...
HM80Mixing Valve Controller
When I replaced my old evotouch controller with the new one, I prepared a scheme of work:
Remove all rad valves.
Replace batteries in all Rad Valves and unbind
Unbind 2 x BDR91 (Boiler and Hot water)
Replace batteries in Cylinder stat and unbind
Replace batteries in 3x DTS92 and unbind
I then followed the guided configuration on the new controller - but must have, somewhere along the line, made an error, because on completion, although everything seemed to work and all RF tests were good, about 6 hours later I got my first "Comms Fault - Boiler Relay."
I then had a few days of problems and didn't record in detail my actions, but by and large it involved rebinding either the boiler relay and/or the hot water relay and/or the cylinder stat in various - and I must admit, increasingly frustrated combinations and sequences. I had to wait approx 6 hours between each rebind to see if the comms fault reappeared - and it was only after reading wonky's contribution that I has success.
So... only myself to blame, but maybe the importance of "hot water before boiler" should be better highlighted.