I'm wondering if the following might also be a contender. I think it's mentioned up thread that firing boiler may not be necessary as long as water can be circulated. A variation on the zone valve at far end approach would be...
- Take boiler control BDR to boiler, and to white wire (NC of auxiliary switch) on remote valve. Bring grey wire (common on switch) back to pump and CH valve. So far everything still works pretty much as is when far valve is closed, except CH valve probably now opens whenever pump is running. I forget whether that is a bad thing or not as the 3 relay scenarios for what is wanted open with what continue to confuse me a bit
. If it really matters then I suspect some similar NC / NO wiring could be done on the CH valve so that boiler can fire pump without opening CH valve, but opening CH valve would also fire pump.
- Use frost stat in suitable location to control that valve on the blue / brown wires. Connect permanent 240V to orange wire (NO on switch). When weather is cold valve opens, bringing 240V to pump and CH valve via auxiliary switch to circulate cold water around opened circuit.
If the rooms happened to call for heat while this valve was open they might not get much unless it had a flow restrictor such as a partially closed gate valve to help balance flow.
The magic white wire is found on 28mm (and 1") valves as it is used in C-Plan wiring which usually has larger pipework for the gravity HW loop, and IIRC the replacement head units which are universal and hence should fit a 22mm valve. I think you could also solder a wire to the unused contact on the switch on old 22mm valves, but I wouldn't be surprised if the new valves have only the minimum amount of required componentry and hence this not being available.
If you wanted to fire the boiler as well then taking the BDR signal down to the remote valve and bringing the return to boiler / pump / CH should achieve that, and you'd then probably want to take the frost stat output via the pipe sensor that you mentioned so that you'd just be taking the chill out of the pipes before turning boiler off.