You're going to need to figure out what sort of configuration you have by tracing the pipes from the boiler. A two port zone valve used in an S-Plan system looks like this typically, and you would most likely have two, but may have more:
https://www.amazon.co.uk/Honeywell-V.../dp/B001ANU6UA
If it's a Y plan system you'll have a valve that looks something like this with 3 ports, in which case you would only have one zone valve:
https://www.amazon.co.uk/Honeywell-V...l+3+port+valve
If you can find either of these and take a picture of them and the nearby pipes that might be helpful.