Hi, I hope this helps you understand how evohome works. Firstly everything talks to the screen, nothing talks to each other. There are two separate areas in the set up, system devices that control your boiler or heat pump when there is a demand and can control heating and hot water zone valves ( not to be confused with UFH zones valves etc, they are zones). Then there is another area of set up called zones or zone options, these devices and thermostats are used to control the flow of heated water to each separate zone or room. None of these zones turn the boiler on directly.
Every zone has an actuator and temperate sensor (thermostat DT92) there is no master thermostat !
When any zone calls for heat the evohome screen sends a signal to one or all the system device relays (BDR91) to trigger the boiler.
Can you list the zones you want and what type of heating they have (ie. UFH, radiator) and I will list what to bind to what.
Hope this helps,