Are you sure the locking latch at the bottom of the HR92 is clicked over to lock the HR92 from removal ? If not, it won't call for heat or adjust the valve position but there won't be any errors messages either...
Next things to check assuming that is OK is look at the valve pin position in the HR92 when it should be getting hot - do this by changing option 10 to a 1. This goes from 0% (valve closed) to 100% (valve open) Any reading higher than about 30-35% should start calling for heat and allowing water to flow.
After that I would check the system summary page in the installer menu (long press on settings) and see what heat demand is show for the zone.
When you say you bound each HR92 one at a time, you didn't go back to the system installer menu between each one did you ?
Q2. I have four zones that have two or more rads/HR92's in each. My problem is the same in each; only one radiator heats up in each of these zones.
When binding them, I did them one at a time and had a 'Success' message for each one. As each zone is large enough to be subject to temp variations at each end, I set each of these zones as multi-room as my understanding was that they could all work away independently of the other/s HR92's.
When you bind multiple HR92's to a zone it will first ask you for the sensor for the zone - bind the first HR92. It will the ask if you have any "additional actuators", this is when you would bind the second HR92.
If you just bound the first HR92, completed that and went back to the installer menu, then went into bind another HR92 to that zone it would actually overwrite the first one. All the HR92's must be done in the same binding "session". Does that make sense ?
Assuming this has been done correctly I would suggest similar to above - go into option 10 and set it to 1 on both HR92's and see what the valve pin position is.
Keep in mind that in multi-room zone mode each HR92 is using it's own sensor so if different ends of the room are at different temperatures it may be correct that one radiator doesn't need to come on. To rule this out just change the set point to be many degrees higher than the room temperature which should cause both radiators to come on. If not, you do have a problem.