If you were using an HGI80 or similar then under the Switches Tab you would see at least 2 relays called CH Valve and Boiler. These track the Heat Demand that is being sent to the BDR91. This isn't visible via the Web API. Heat Demand is different to the actual switching of the boiler, which is actually performed using TPI. As it turns out, I have just submitted a PR to the Domoticz project to create additional Zone Relay devices that actually attempt to track the Switching On/Off of the BDR91 i.e. stay in step to the LED Green light.
Another thing to note is boiler being switched on is different from Flame being On. So generally Heat Demand > BDR91 TPI > Flame On. Sadly, all of this can only be tracked via sniffing the radio signals and not accessible via the web API.