Yes, that's correct.
Yes, the boiler-BDR91 responds to heat demand, as always.Will that then use the new BDR91 to switch on the UFH pump, but also call the existing BDR91 connected to the boiler in order to send hot water into the UFH?
You should not need the motorised valve. The UFH manifold is designed in such a way that water circulating as a result of the boiler-pump being active will not circulate in the floor unless the UFH pump is on. The top bar on the manifold 'short circuits' the UFH circulation in this case.At times I want the UFH to be off. Would the pump not running keep hot water from entering the loop, or could I use a spare honeywell motorized valve and connect that to the new BDR91 also? That way the motorised valve and the pump would both be run when the new BDR91 is switched on, and remain shut to heated water when it is off.