I don't think the number of radiator valves make a difference to the learning time.
The individual radiator controllers all have some intelligence built into them (a self tuning PID controller) and it learns over time the response characteristics of the room - how much over the air heat demand and water flow causes the room temperature to rise at a certain rate, how early before the target temperature it has to start backing off to avoid overshoot etc...
Load scaling throws it a curve ball where the heat demand request from the individual radiator controllers is intelligently "scaled down" from what they actually asked for. So the adaption process is largely about the radiator controllers learning that they need to send a higher heat demand than they used to to get the same result. (Also the load scaling itself performed in the controller has its own separate adaption process)
So typically the initial reaction to enabling load scaling for the first time would be for some of your rooms to undershoot their targets by maybe a degree or so and then gradually adjust to get it right. Similar to what you might see if you got a sudden cold snap where the targets might be undershot for a day or so.